Generates carbon dioxide, HCl, water, phosgene, Hydrogen peroxide, bleach; poured down the drain, Decomposes to release hydrogen sulfide, sulfur dioxide and carbon dioxide, Neutralize it with bleach or hydrogen peroxide first, Harmful to organisms due to its ability to weaken S-S bonds in various tissues, Generates oxidation products and lots of soot, Generates carbon oxides, water vapor and soot, Toxic to wildlife and dangerous for water bodies as it floats, Generates carbon oxides, water vapor, soot and bromine vapors, Strong dilution; Oxidation with Fenton's reagent, Generates carbon oxides, water vapor, soot and nitrogen vapors, Considered to be toxic to wildlife, but not much is known about its effects, Neutralization with diluted aq. Inorganic anions, based on halogens, sulfur, phosphorus, nitrogen, carbon and silicon can be flushed down the drain with lots of water. WebTests showed that a solution made up from equal parts of copper sulfate and sodium chloride (i.e. Lower Explosive Limit (LEL): data unavailable, Upper Explosive Limit (UEL): data unavailable, Autoignition Temperature: data unavailable, Vapor Density (Relative to Air): data unavailable, Ionization Energy/Potential: data unavailable, National Oceanic and Atmospheric Administration. Lists of various chemical compounds that can be safely released in the ground or down the drain can be found here, here or here. cooking salt) activates the etch by diminishing the bond with water. WebExcerpt from ERG Guide 171 [Substances (Low to Moderate Hazard)]: IMMEDIATE PRECAUTIONARY MEASURE: Isolate spill or leak area in all directions for at least 50 NaOH; Strong dilution; Oxidation with Fenton's reagent, Generates carbon oxides, water vapor, soot, sulfur oxides and HCl fumes, Incineration; Sodium pyrosulfite; L-cysteine, Generates carbon oxides and water vapors; some will evaporate when heated, Dilution in a more flammable solvent, followed by incineration; Oxidation with Fenton's reagent, Gives off carbon monoxide, dioxide, ammonia, acetonitrile, hydrogen cyanide, Addition to water followed by heating, yielding acetic acid and ammonium chloride, Anhydrous conditions yields ammonium chloride and acetonitrile; In presence of water acetic acid and ammonium chloride are formed, Flammable (high concentrations), no dangerous combustion products, Safe, biodegradable; avoid dumping large amounts, acidifies soil, Flammable, no dangerous combustion products, Biodegradable; avoid dumping large amounts, acidifies soil, Oxidation/incineration, reducing, photolysis, Biodegradable, though not advised for large amounts, Fenton's reagent; Aqueous solution of excess sodium hydroxide, All treatments give some hydrogen cyanide fumes, Toxic to all life due to its cyanide/nitrile group; does not quickly break down in environment, Mixed with a more flammable solvent and incinerated, Generates smoke, carbon dioxide and water vapors, Relative safe, biodegradable; Occurs naturally in small amounts, Burn products include hydrogen chloride which is corrosive, Extremely toxic and corrosive to organisms and environment, Gives off carbon dioxide and water vapors, Addition of a base, which causes polymerization, Burns in the presence of oxygen releasing carbon oxides, water, and various other organic products, Burning, dumping in ground; Desorption by heating it to high temperature and reuse, Unless it adsorbed dangerous volatile compounds or heavy metals, it can be used as a fertilizer (powdered form); Less effective as beads or pellets, Safe, biodegradable; nourishment for many organisms, Diluted with a flammable solvent, like ethanol or acetone and burned; Epoxidation and hydrolysis to glycerol, Loses magnetism when heated and melts at high temperatures, Nickel and cobalt are harmful for the environment, Generates smoke, carbon dioxide and water vapor, Treatment with water, precipitation with a base, No effect; Water solutions however will give off hydrogen chloride vapors, Treatment with water, precipitation with a base; recycling of iodine, No effect; Water solutions however will give off hydrogen iodide and iodine vapors, Incineration outside; Treatment with water, recovery of isopropanol and aluminium oxide/hydroxide or incineration of isopropanol, Melts and decomposes to give various ketones and isopropanol which may ignite; leaves behind alumina residue, Increases level of aluminium from soil, corrosive and harmful to organisms, Pyrolysis; Aqueous ammonia or alkaline hydroxide solution, Not always required, can be dumped in trash, Increases level of aluminium in soil, toxic to animals in large quantities, Burns in air, releasing fumes of phosphorus pentoxide and aluminium oxide, as well as traces of phosphine if any moisture is present, Releases phosphine gas on contact with water, which is deadly to organisms, Releases sulfur oxides at high temperature, Dilute it first; neutralization with a base first is recommended, Increases the aluminium concentration in soil and water, lowers pH, Releases hydrogen sulfide on contact with water, which is toxic to organisms, Burns, may detonate in the presence of metallic impurities, like copper, brass, While ammonium nitrate is a good nitrogen source for plants, TNT is very harmful for wildlife, Not required, can be discarded in any way, Pyrolysis gives nitrogen and carbon oxides, Not required, can be dumped in ground; Pyrolysis done outside, Pyrolysis gives nitrogen, water and carbon/nitrogen oxides, Little is known about its environmental impact, Not required, can be dumped in ground; Careful and controlled pyrolysis, Pyrolysis gives nitrogen, water and carbon/nitrogen oxides; may explode at high temperatures, Safe, nitrogen source for plants; Guanidine derivates occur in guano, Burns, may detonate in the presence of metallic impurities, like copper, While ammonium nitrate is a good nitrogen source for plants, the aluminium, TNT and other impurities present are harmful for wildlife, At high concentrations may generate nitrogen oxides, Not possible (gaseous), safe to pour (as solution), Not possible (gaseous), safe to pour (as solution); Good nitrogen source for plants, Slowly volatilizes and explodes at 400 C releasing nitrogen, hydrogen and ammonia gasses, Decomposes on heating releasing carbon dioxide, ammonia fumes and water vapors, Neutralize it with ammonia; can then poured down the drain, Decomposes to release sulfur oxides and ammonia, Yes, though recommended to neutralize first, Acidic, but once neutralized good nitrogen and sulfur source for plants, While it can be diluted and poured down the drain, it's recommended to neutralize it first; hydrogen peroxide and ammonia can be used to safely neutralize it, Decomposes to release sulfur dioxide and ammonia, Oxidation of aqueous ammonium bisulfite to bisulfate can reduce the amount of dissolved oxygen from water bodies and will lower water pH, Decomposes on heating releasing nitrogen, water, oxygen and hydrogen chloride, sometimes explosively, Decomposes on heating releasing ammonia and hydrogen chloride, Safe, good fertilizer (nitrogen source); May prove unsuitable to chloride sensitive plants, Reducing with a reducing agent, such as sodium metabisulfite, sulfite, bisulfite, ascorbic acid, at acidic pH, Decomposes, the famous volcano reaction, releasing nitrogen gas, water vapors, fine particulates of unburnt ammonium chromate, leaving behind Cr(III) oxide, Cr(VI) ions are carcinogenic and very toxic to organisms, Reducing with a reducing agent, such as sodium metabisulfite, sulfite, bisulfite, ascorbic acid at acidic pH, Decomposes, the famous volcano reaction, releasing nitrogen gas, water vapors, fine particulates of unburnt ammonium dichromate, leaving behind Cr(III) oxide, Not required; Slaked lime can be used to precipitate calcium phosphate, Safe, good fertilizer (nitrogen and phosphorus source), Decomposes on heating to release nitrogen, water and oxygen; may explode if heated too high, While it may be a good fertilizer, its environmental effects are unknown, Decomposes in several steps, releasing ammonia, water, cyanogen, ferric oxide, in air, Low toxicity, environmental effects unknown, Alkali hydroxide, carbonate, sulfate; heating in the presence of a base, Decomposes on heating to release ammonia, carbon monoxide, hydrogen cyanide and water, Alkali hydroxide, carbonate, sulfate; Dilution, poured down the drain, Decomposes on heating to release ammonia, water, leaving behind MoO, Diluted cooled hydrogen peroxide solution, Harmful to organisms, especially aquatic ones, Safe, good fertilizer (nitrogen, iron and sulfur source); May cause algal bloom in water bodies however, Safe, good fertilizer (nitrogen source); May cause algal bloom in water bodies however, Alkali hydroxides; strong dilution followed by heating; will slowly decompose even at room temperature, so you may leave it in a safe area and let it decompose, Decomposes or detonates, releasing nitrogen and water vapors, Decomposes quickly in environment, especially at low pH, Alkali hydroxide, carbonate, sulfate; pyrolysis in the presence of a base, Decomposes on heating to release ammonia, carbon monoxide, oximide, hydrogen cyanide and water vapors, May pose a threat to wildlife in large amounts; Occurs naturally in guano, Reduction with metallic iron under UV light in the absence of air; Heating perchlorate at 200 C with metallic iron for several hours, Decomposes to release nitrogen, water vapors, oxygen and hydrogen chloride, Dissolution in water, followed by reduction with sulfur dioxide or sodium sulfite, thiosulfate or metabisulfite, Detonates above 60-110 C, releasing nitrogen, water vapors and a smoke of manganese dioxide, Strong oxidizer and explosive, hazardous for wildlife, Pyrolysis, hydrolysis, various reducing agents, Decomposes at 120 C releasing sulfur and nitrogen oxides, oxygen and ammonia, Not required; Strong dilution is sufficient, Decomposes on heating to release ammonia, sulfur dioxide, sulfuric acid vapors, Considered to be environmentally friendly due to its degradation to non-harmful residues, Not required; Calcium hydroxide can be used to precipitate calcium sulfate, Safe, good fertilizer (nitrogen and sulfur source); slightly lowers the soil pH, Decomposes releasing hydrogen sulfide and ammonia, Extremely toxic for wildlife; Dangerous for the environment (DSD), Not required, simply pour down the drain; Bleach or hydrogen peroxide can be used if desired, Oxidation of aqueous ammonium sulfite to sulfate can reduce the amount of dissolved oxygen from water bodies; otherwise, safe, used as fertilizer, Precipitation with sodium hydroxide to less sodium fluorides, Emits very toxic fumes of hydrogen fluoride, nitrogen oxides and ammonia, Dilute then pour down the drain; Bleach or hydrogen peroxide can be used if desired, Decomposes to release sulfur dioxide, ammonia, water vapors, May be harmful for aquatic life; safe, used as fertilizer, While ammonium nitrate is a good nitrogen source for plants, the fuel oil (FO) from its composition is harmful for wildlife, Gives off carbon oxides, soot, nitrogen and or nitrogen oxides and water vapor, Dilution with a solvent, followed by incineration; Oxidation with an oxidizing solution, like Fenton's reagent, Gives off carbon oxides, soot and water vapor, While ammonium nitrate is a good nitrogen source for plants, nitromethane and methanol may be harmful for wildlife, Sublimes and decomposes, releasing carbon oxides, water vapors, soot, anilline, Mixed with a more flammable solvent and safely incinerated; Controlled oxidation with Fenton's reagent. at high temperatures, Unless contaminated, good source of zinc for plants, though a bit too acidic; may lower soil pH, Breaks down to zinc oxide and carbon oxide at high temperatures, Unless contaminated, good source of zinc for plants, though a bit too alkaline, Gives off hydrochloric acid fumes if moist, Chlorides are dangerous for chloride-sensitive plants in large quantities, Sodium, potassium or ammonium carbonate/bicarbonate to precipitate zinc carbonate which is inert; recovery of alkali nitrates, dilution of zinc carbonate and poured down the drain, Decomposes to zinc oxide, releasing nitrogen dioxide and oxigen, May pose a threat to aquatic life in large quantities; may cause unwanted algal bloom; source of zinc and nitrogen to plants, Not required; Weak acids can be used to dissolve zinc oxide stains to soluble zinc compounds, Turns the oxide yellow at high temperatures; process is reversible, May pose a threat to aquatic life in large quantities, Precipitation with a soluble hydroxide; Reduction of perchlorate to chloride, Gives off chlorine oxide fumes, leaving behind zinc oxide slag; may decompose violently if organic contaminant present, Source of zinc and phosphorus for wildlife, Not always required; Zinc metal can be recovered through electrowinning and the diluted sulfuric acid neutralized with a base, Unless contaminated, is a good source of zinc for plants, Dissolving it in water, followed by precipitation of zirconium dioxide by adding an alkali, Potentially harmful; Nitrates may serve as nourishment for plants; Zirconium displays moderate toxicity, Decomposes releasing HCl and water vapors. Small quantities. It's best however, to avoid dumping large quantities of waste, as the reaction in exothermic and may splash or volatilize some of the waste, so it's best to perform the neutralization in small steps. Title: Safety Data Sheet for Magnesium Sulfate (MgSO4) Solution (100 mM) (B1003) Author: New England Biolabs, Inc. Corrosive and dangerous on direct contact with wildlife; Reaction with water will lead to phosphoric acid, highly corrosive and dangerous. WebHazardous decomposition products:Zinc or zinc oxides. All are noncombustible. They usually do not react as either oxidizing agents or reducing agents but such behavior is not impossible. They react as acids to neutralize bases. Zinc Sulfateis a colorless, odorless, crystalline powder. It is used in making rayon, as a wood preservative, and as an analytical reagent. It is also used as a dietary supplement, and in herbicides, water treatment, fireproofing, deodorant, cosmetics and fertilizers. Reasons for Citation WebPlace the mixture in a container such as a sealed plastic bag; Throw away the container in your trash at home; and Delete all personal information on the prescription label of Zinc sulfate is also obtained as a hexahydrate, ZnSO4.6H2O, and as a heptahydrate ZnSO4.7H2O. Section 7: Handling and IF IN EYES: Rinse cautiously with water for several minutes. If you live in an apartment block, you only have the drain. These should be converted to the +3 oxidation state; hydrogen peroxide as well as sulfites or thiosulfate will do this, which is typically the least harmful, preferably to chromium(III) oxide. Another simple solution is to reduce the ions back to the metal. 3. Disposal Considerations Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. ALWAYS POUR THE ACID IN WATER AND NOT THE OTHER WAY AROUND! NaOH; Oxidation with Fenton's reagent, Burns and decomposes to release combustion gasses and soot, may explode, Extremely toxic to the environment, especially for animals, Careful and controlled destruction using an oxidizing solution, Burns and decomposes to release combustion gasses and soot, Dissolved in a more flammable solvent and incinerated. However, this merely is a method to prevent the heavy metals from being released in the environment and is not a permanent way of disposal. If magnetic, a magnet can be used to scoop all the pieces, Stainless steel alloys contain chromium which will slowly leak in the environment and may increase the level of chromium in the environment; Some SS alloys may have nickel which is harmful to the environment, Safe, biodegradable; Nourishment for almost all organisms, Recycling; Steel waste don't require chemical neutralization as it's mostly iron which has low environmental impact. Office of Response and Restoration, Decomposes at high temperatures to yield carbon oxides, water vapors, soot, VOCs, etc. Organic salts, such as acetates and oxalates can be pyrolyzed to carbonates and water vapors. Web2. Efflorescent in air. They can, however, be converted to aluminium sulfate, which is safe to dispose of in soil, though it will cause a decrease in pH (it is used as a fertilizer for this purpose), and in diluted form can be poured down the drain, as at low concentrations it's Before neutralizing them, always dilute the acid first, to limit splashing or boiling the acid. Sweep up spill and place in sealed bag or container for disposal. Salts of hydrochloric, sulfuric, phosphoric acids can be further diluted then safely poured down the drain, or recycled if you want. WebPackage lots. Evacuate personnel and secure control entrance to the area. 5 Any drug that contains the word hydromorphone. For quicker results, alkali bases can be neutralized with any acid, though for practical and economical purposes, acetic acid or citric acid are sufficient. Aluminium compounds generally should not be disposed in the sewage. The soluble salts of halogen acids and oxoacids (except perchloric and chloric acids) can be safely poured down the drain. To overcome this, you can use a freshwater foot-bath before the chemical foot-bath to get rid of any organic material. Keep the copper carbonate for other experiments or bin it as it is basically inert. The resulting solutions contain moderate concentrations of hydrogen ions and have pH's of less than 7.0. You probably dont even need to filter it once it has reacted with the sodium bicarbonate, just pour it away. However, as the carbonate is formed, it will creep out of the flask, covering it. WebAvoid release to the environment. Copper salts are dangerous to the environment and should be reduced with iron to elemental copper, that can be reused, and the iron salts produced are less toxic. National Ocean Service, After you diluted the acid, dissolve the base in water or, if it's insoluble, add just enough water to turn it into a suspension. Inhalation of dust causes irritation of nose and throat. This section provides a listing of alternate names for this chemical, Aqueous solutions are acidic. Place in a separate labeled container for recycling or disposal. Decomposes at very high temperatures to yield carbon oxides, water vapor, soot, VOCs, etc. Chromium dioxide may be another feasible option, as it is found in cassette tapes and can be recycled with them. Examples of these are sulfide, sulfate, chloride, chlorate, nitrate, nitrite, thiocyanate.[1]. A good rule of thumb for transition metals is to convert solutions of their ions to the insoluble carbonate or oxide, often one of the most stable and nontoxic forms of these elements, prior to disposal. WebZINC sulfate heptahydrate | H14O11SZn | CID 62640 - structure, chemical names, physical and chemical properties, classification, patents, literature, biological activities, safety/hazards/toxicity information, supplier lists, and more. SDS (Sodium Dodecyl Sulfate) (up to 1-25% concentration) Sodium carbonate/Sodium hydrogen carbonate. Sometimes it is an option to purify waste products into chemicals that are pure enough to be used again. Since it's magnetic, a magnet can be used to scoop all steel leftovers, Some steel alloys contain nickel which will leak in the environment which is harmful to the environment, Any acid; Not required; Can be safely dumped in trash, Breaks down to strontium oxide and carbon dioxide at high temperatures; reverts as it cools, Strontium has little effect on environment, Not required; Any soluble carbonate or sulfate, Not required; May be converted to strontium sulfate or just dumped in soil, Breaks down to strontium oxide, oxygen and nitrogen dioxide at high temperatures, Will burn grass on contact; strontium has little effect on environment, Decomposes to strontium oxide at very high temperatures, Low environmental impact, occurs naturally, Careful and controlled destruction using an oxidizing solution; bubbling chlorine in a dil. The information posted in this article is merely a collection of observations from various amateur chemists and is NOT meant for professionally disposing large amounts of chemicals and should NOT be used as a guideline on neutralizing reagents. Currently there are nine products EXALGO. Place in a separate labeled container for recycling or disposal. WebIf Zinc is spilled, take the following steps: f Evacuate personnel and secure and control entrance to the area. SECTION 11 : Toxicological information Acute Toxicity: Oral: 7779-88-6 LD50 Oral - Rat - 1,190 mg/kg Chronic Toxicity: No additional information. Before discarding waste, think about what all it contains, and if there is some way that it could be used. Wash spill area after pickup is complete. (USCG, 1999). Nickel and perchlorates are toxic to environment, Not required; can be dumped in trash or taken to waste disposal centers, Yes (if pure); No (if it contains cobalt), Toxic to the environment if it contains cobalt, Generates carbon oxides, nitrogen fumes; May corrode metal container, if done in one, May cause uncontrolled algae growth in water bodies, Decomposes when burned; May explode if heated at high temperatures, Safe, good fertilizer; May cause uncontrolled algae growth in water bodies, Water, iron(III) oxide, manganese dioxide, Decomposes when heated to high temperatures, releasing water vapor, Yes, though not recommended in large quantities, Irritant and corrosive to large organisms, kills small organisms, Not required; should be taken to disposal facilities, Not useful; Turns into oxides of lower states at high temperatures, Not required; and oxidizing mixture may be used to oxidize it completely if desired, Decomposes above 250 C to release carbon dioxide, water vapors and soot, There is little data available for its environmental effects, doesn't appear to be toxic, Lethal to small animals and toxic to larger ones in small amounts; Not suspected to be bioaccumulative, Uncomposted wood is harmful for environment, especially sawdust, Melts at 70 C and gives off harmful cadmium fumes at high temperatures, While bismuth and tin don't present great hazard to environment, lead and cadmium do, Oxidation with Fenton's reagent; Incineration, best with an afterburner, Burns in air, to release combustion gasses, soot and VOCs, Toxic to wildlife and hazardous to water bodies, Cannot be digested by most lifeforms, otherwise little to no toxicity to most organisms; It is however known to be fatal to dogs and some birds, Recycling; Traces of zamak waste can be dissolved with nitric acid, followed by neutralization of leftover acid, recovering copper and zinc via electrowinning, Not useful; melts above 380 C and may fume, Low quality zamak may contain lead or cadmium which are harmful to the environment, Unless contaminated with hazardous compounds, it poses little danger to environment, Breaks down to zinc oxide, carbon oxides, water, acetone, acetic anhydride (?) As such, this method is generally considered a last resort in disposal, and it's mostly used for cleaning rather than disposal. The resulting solutions contain moderate concentrations of hydrogen ions and have pH's of less than 7.0. WebSaline solution. Boils and breaks down to bromine, hydrogen bromide and phosphorous acids in the presence of air/moisture, Suspension of calcium hydroxide, sodium thiosulfate, cooled; PCl, Sodium thiosulfate solution/suspension; PI, Very toxic and corrosive to organisms and rocks, Suspension of calcium hydroxide, sodium thiosulfate, cooled; POBr, Suspension of calcium hydroxide, sodium thiosulfate, cooled; POCl, Oxidation with oxidizing solutions, such as chromic acid, Fenton's reagent, piranha solution, Hydrolysis with aqueous sodium hydroxide; oxidation with Fenton's reagent; Containers with dry picric acid should be taken by professionals and safely detonated in a remote location, Gives off carbon dioxide, water vapors, soot, VOCs, Strongly diluted with a flammable solvent and safely incinerated, Gives off carbon dioxide, water vapors, may explode if impurities present, Not required; Can simply be dumped in trash, Generates toxic fluorine, hydrogen fluoride, fluorocarbons and carbon oxide vapors, Resistant to most corrosive chemicals, cannot be digested by wildlife. Other: See actual entry in RTECS for complete information. Copper and Zinc have specific discharge limits It is used in the production of rayon, as a feed supplement, and as a fertilizer ingredient. Breaks down rapidly in the environment due to air and microorganisms, yielding sulfides and sulfates. Likewise, it's forbidden to burn certain materials in open air, such as aromatic compounds or organosulfur compounds and for those, special incinerators are a must. (Zinc sulfate) Transport hazard class(es) Class: 9 Miscellaneous dangerous substances and articles Packing group:III Environmental hazard: Transport in bulk: Name: Marine Pollutant & indicates that no RQ is assigned to this generic or broad class, although the class is a CERCLA hazardous substance. Diluted then safely poured down the drain, or recycled if you want dioxide may be another option... 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Sodium Dodecyl sulfate ) ( up to 1-25 % concentration ) sodium carbonate/Sodium hydrogen carbonate always POUR the ACID water! In disposal, and as an analytical reagent discarding waste, think about what it! Sealed bag or container for recycling or disposal thiocyanate. [ 1 ] the,... Entry in RTECS for complete information for other experiments or bin it as is. ( except perchloric and chloric how to dispose of zinc sulfate solution ) can be pyrolyzed to carbonates and water vapors soot! Additional information: Toxicological information Acute Toxicity: No additional information fireproofing, deodorant, cosmetics and fertilizers recycling. Have pH 's of less than 7.0 halogen acids and oxoacids ( except perchloric and chloric acids ) can pyrolyzed! Compounds generally should not be saved for recovery or recycling should be managed in an apartment block, you have! Of these are sulfide, sulfate, chloride, chlorate, nitrate, nitrite, thiocyanate. [ ]! Probably dont even need to filter it once it has reacted with the sodium bicarbonate, POUR... Purify waste products into chemicals that are pure enough to be used bicarbonate, just POUR it away that pure., odorless, crystalline powder such behavior is not impossible found in cassette tapes and can be safely down! Used in making rayon, as it is found in cassette tapes and can be safely down! Covering it an apartment block, you only have the drain and secure and control entrance to the.!, and if in EYES: Rinse cautiously with water for several minutes ions and pH. Once it has reacted with the sodium bicarbonate, just POUR it.!, such as acetates and oxalates can be recycled with them, Decomposes at very temperatures... In disposal, and in herbicides, water vapors f evacuate personnel and secure and control entrance to the.... Handling and if there is some WAY that it could be used, it creep... 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Eyes: Rinse cautiously with water is not impossible aluminium compounds generally should not be saved for recovery recycling... See actual entry in RTECS for complete information only have the drain perchloric and chloric acids ) be! Inhalation of dust causes irritation of nose and throat phosphoric acids can be recycled with them equal of... 11: Toxicological information Acute Toxicity: No additional information showed that a solution made up from equal parts copper!
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